What is Deionization and How does it Work?

What Is Deionization (DI)?

Ion exchange for ultra‑low conductivity water

DI resin removes dissolved mineral ions from water using ion exchange. In deionization, a cation resin (H⁺ form) replaces positive ions (Ca²⁺, Mg²⁺, Na⁺), and an anion resin (OH⁻ form) replaces negative ions (Cl⁻, NO₃⁻, SO₄²⁻, HCO₃⁻, silicate). The released H⁺ and OH⁻ combine to form H₂O, yielding very low conductivity water suitable for labs, manufacturing, aquariums, and spot‑free rinsing.

Exchanges H & OH–
RO → DI Advantage
Two‑Bed & MB Polish
Silica Control (Type I)

Important Takeaways

Ion exchange replaces ions

Cation (H⁺) swaps positive ions; anion (OH⁻) swaps negative ions; H⁺ + OH⁻ → H₂O.

RO + DI is the sweet spot

RO removes 95–99% of load; DI polishes to ultra‑low conductivity and lowers cost per gallon.

Choose two‑bed vs. mixed‑bed

Two‑bed for bulk demineralization; mixed‑bed for the highest resistivity at point‑of‑use.

Monitor to time changeout

Rising conductivity (or TDS) after DI signals media exhaustion.

How Does Deionization Work?

Deionization (DI) uses ion exchange resins to replace dissolved ions with hydrogen (H⁺) and hydroxide (OH⁻). The released H⁺ and OH⁻ combine to form H₂O, driving conductivity down to very low levels.

  • Cation resin (H⁺ form): Exchanges positive ions like Ca²⁺, Mg²⁺, Na⁺, Fe²⁺/Fe³⁺.
  • Anion resin (OH⁻ form): Exchanges negative ions like Cl⁻, NO₃⁻, SO₄²⁻, HCO₃⁻, silicate.
  • Configurations: Two‑bed handles bulk removal; a mixed‑bed polisher achieves the lowest conductivity. Pairing RO → DI lowers cost per gallon.

Read the in‑depth guide: Deionization Resin Explained

Cation vs. Anion DI Resins

DI relies on two resin types working together: a strong acid cation resin (H⁺ form) removes positive ions (Ca²⁺, Mg²⁺, Na⁺), and a strong base anion resin (OH⁻ form) removes negative ions (Cl⁻, NO₃⁻, SO₄²⁻, HCO₃⁻, silicate). The H⁺ and OH⁻ released combine to form H₂O, driving conductivity very low.

Deionization Diagram

Deionization diagram showing cation (H+) then anion (OH-) exchange to produce H2O

NaCl path: cation replaces Na⁺ with H⁺ (H⁺ + Cl⁻) → anion replaces Cl⁻ with OH⁻ → H⁺ + OH⁻ → H₂O.

  • Type I vs. Type II anion: Type I minimizes silica leakage for ultra‑low conductivity; Type II offers higher capacity but slightly more silica leakage.
  • Two‑bed vs. mixed‑bed: Two‑bed handles bulk demineralization; a mixed‑bed polisher at point‑of‑use reaches the highest resistivity.
  • Best practice: Feed DI with RO to extend resin life 10–20× and stabilize water quality.
Cation vs. Anion Resin Differences
Cation (H⁺ form) Anion (OH⁻ form)
Holds H⁺; swaps for positive ions Holds OH⁻; swaps for negative ions
Removes Ca²⁺, Mg²⁺, Na⁺, Fe²⁺/Fe³⁺ Removes Cl⁻, NO₃⁻, SO₄²⁻, HCO₃⁻, silicate

What Is Deionized Water Used For?

Common applications that benefit from very low conductivity and low silica water, including labs, aquariums, spot‑free rinsing, and industrial/boiler makeup.

Scientist working in a lab with DI water

Labs & Instruments

Type I/II lab water, rinsing, and support for HPLC/ICP/AA workflows.

Home aquarium using RO/DI water

Aquariums (RO/DI)

Stable, zero‑TDS base water for reef aquariums and sensitive species.

Spot‑free rinse car wash using DI water

Spot‑Free Rinse

Detailing and window cleaning with no mineral spotting after dry‑down.

Industrial boiler makeup water requiring low silica and low conductivity

Boiler Makeup / UPW

Low silica, low conductivity feed for reliability and ultra‑pure processes.

Compare Water Deionization Options

Two‑bed DI vs Mixed‑bed DI vs RO + DI comparison table
Feature Two‑Bed DI Mixed‑Bed DI RO + DI
Purity level Low‑to‑very‑low TDS Highest (polish) Highest + best cost
Best for Bulk demineralization Point‑of‑use polish Economical ultra‑pure
Regeneration On‑site or service Replace/service DI lasts 10–20× longer
Silica control Good (Type I anion) Excellent Excellent

When to Use DI Systems (vs. RO or Softening)

Quick guide: Softening prevents scale (hardness only), RO removes most dissolved solids, and DI polishes remaining ions to ultra‑low conductivity. Most systems pair RO → DI for the best cost per gallon.

Water softener system for hardness control

Water Softening

Stops hardness scaling (Ca²⁺/Mg²⁺ → Na⁺/K⁺). TDS remains.

  • Use when: Scale on fixtures/appliances; protect RO membranes.
  • Delivers: Scale‑free water; no change to TDS/conductivity.
  • Pair with: RO (pre‑treat) for better membrane life.
Reverse osmosis system for dissolved solids reduction

Reverse Osmosis (RO)

Removes 95–99% of dissolved solids and lowers DI cost per gallon.

  • Use when: You need big TDS reductions and better taste.
  • Delivers: 95–99% TDS removal; strong overall purity.
  • Pair with: DI to reach ultra‑low conductivity.
Deionization cartridge for ultra-low conductivity

Deionization (DI)

Exchanges remaining ions to achieve very low conductivity for sensitive uses.

  • Use when: Labs, aquariums, spot‑free rinse, low silica needs.
  • Delivers: Very low conductivity/near‑zero TDS water.
  • Pair with: RO to extend resin life 10–20×.

Learn More About Deionization

Want the full science and sizing guidance? Read our in‑depth guide covering mechanism, EBCT, silica, and monitoring best practices.

Frequently Asked Questions

Get answers to common questions about deionization resin and DI water

What is DI resin?

An ion exchange media that replaces dissolved ions with H⁺ and OH⁻, which combine to form H₂O for very low conductivity water.

Do I need RO before DI?

For most users, yes. RO removes the bulk of dissolved solids so DI lasts longer and costs less per gallon.

Two‑bed or mixed‑bed?

Use two‑bed for bulk demineralization and a mixed‑bed polisher for the highest resistivity at point‑of‑use.

Does DI remove silica?

Yes. Strong base anion resin reduces silica; choosing Type I anion resin minimizes silica leakage. A mixed‑bed polisher achieves very low silica, especially when DI follows RO.

How long does DI resin last?

It depends on feed water quality and load. When DI follows RO, resin life is typically 10–20× longer. Monitor product resistivity or TDS to determine actual changeout intervals, and use a calculator like ours to estimate resin life and total gallons: Deionized Water Filter Calculator.

How do I know when to replace DI?

Watch resistivity or TDS after DI; rising conductivity (or TDS) indicates exhaustion. Color‑change resin helps but always confirm with a meter.